Focus on properties and applications of perovskites
نویسندگان
چکیده
Missouri University of Science and Technology, USA 2 Tsinghua University, People’s Republic of China University of Rennes 1, France E-mail: [email protected], [email protected], [email protected] and octavio. [email protected] Perovskite materials with the same crystal structure as CaTiO3 exhibit intriguing and unusual physical properties that have been extensively studied for both practical applications and theoretical modeling. From the discovery of ceramic high-temperature superconductors to the organic–inorganic semiconductors for high-efficiency photovoltaics, the materials science and applications of perovskites have been a very broad research area open to many revolutionary discoveries for new device concepts. The impressive range of structure and property interplay of perovskites makes them an excellent research field for studies in materials science, physics and solid state chemistry. Structurally, such materials form various crystals including oxide and organometallic perovskites, spinels, and pyrochlores, to name just a few. Many different types of lattice distortions can occur owing to the flexibility of bond angles within the ideal perovskite structure. A broad range of novel functional materials and device concepts can be envisaged through fundamental understanding of the relationships between the structural and chemical compatibility, thermal stability, solid solubility and lattice strain. In this focus issue of Science and Technology of Advanced Materials, we present articles that cover a wide range of topics on perovskites, which include ferroelectric, dielectric, pyroelectric, piezoelectric, magnetic, catalytic, photovoltaic and electronic conduction properties. While this focus issue may not exhaust the many aspects of perovskite materials, it does highlight our fundamental understanding and underscore many exciting developments in this field. We hope that these articles will stimulate more interest in perovskites and help readers better understand some important scientific and technological issues related to perovskite materials. Special thanks are due to the authors and manuscript reviewers. Without their efforts, this focus issue would not have been completed.
منابع مشابه
Investigation of effect of magnetic ordering on structural and electronic properties of double perovskites Sr2BWO6 (B = Co, Ni, Cu) using ab initio method
Structural and electronic properties of double perovskites Sr2BWO6 (B = Co, Ni, Cu) were studied for each of three magnetic configurations nonmagnetic, ferromagnetic, and antiferromagnetic by using density functional theory in generalized gradient approximations (GGA) and strong correlation correction (GGA + U). Due to magnetic transition from antiferromagnetic to nonmagnetic phase, an electr...
متن کاملProgress on lead-free metal halide perovskites for photovoltaic applications: a review
ABSTRACT Metal halide perovskites have revolutionized the field of solution-processable photovoltaics. Within just a few years, the power conversion efficiencies of perovskite-based solar cells have been improved significantly to over 20%, which makes them now already comparably efficient to silicon-based photovoltaics. This breakthrough in solution-based photovoltaics, however, has the drawbac...
متن کاملStructural, Magnetic and Catalytic Properties of Non-Stoichiometric Lanthanum Ferrite Nano-Perovskites in Carbon Monoxide Oxidation
Perovskite-type oxides of LaFe(1+x)O(3+δ) (x = 0.0, 0.2, 0.5 and 0.7) were synthesized by citrate sol–gel methodto ensure the formation of nanosized perovskites. The physicochemical properties of these LaFe(1+x)O(3+δ)materials were characterized by thermal gravimetric/differential analyses, Fourier transform infraredspectroscopy, X-ray powder diffraction, scanning electron and...
متن کاملChitin and Chitosan: Structure, Properties and Applications
Chitin and chitosan are the most abundant natural amino polysaccharide that are non-toxic, biodegradable and biocompatible. They have become of great interest not only as an underutilized resource, but also as a new functional material of high potential in various fields. They are biopolymers having immense structural possibilities for chemical and mechanical modifications to generate novel pro...
متن کاملPressure-induced dramatic changes in organic–inorganic halide perovskites
Organic-inorganic halide perovskites have emerged as a promising family of functional materials for advanced photovoltaic and optoelectronic applications with high performances and low costs. Various chemical methods and processing approaches have been employed to modify the compositions, structures, morphologies, and electronic properties of hybrid perovskites. However, challenges still remain...
متن کامل